The structure of inorganic radicals
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The structure of inorganic radicals an application of electron spin resonance to the study of molecular structure by P. W. Atkins

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Published by Elsevier Pub. Co. in Amsterdam, New York .
Written in English

Subjects:

  • Radicals (Chemistry) -- Spectra.,
  • Electron paramagnetic resonance.,
  • Molecular spectroscopy.,
  • Molecular structure.

Book details:

Edition Notes

Includes bibliographies.

Statementby P. W. Atkins and M. C. R. Symons.
ContributionsSymons, M. C. R. joint author.
Classifications
LC ClassificationsQD471 .A83 1967
The Physical Object
Paginationx, 280 p.
Number of Pages280
ID Numbers
Open LibraryOL5989888M
LC Control Number66020555

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The first three chapters deal with the molecular structure determination by neutron and X-ray diffraction, high-pressure vibrational spectroscopy, and electronic Raman transitions of rare earth ions. Other chapters explore the potential of electron spin resonance spectroscopy for inorganic radical and radical ion determination, as well as the application of electron spin resonance for coordination . Advanced Inorganic Chemistry by Wikibooks. This book covers the following topics: Symmetry Elements, Molecular Point Groups, Matrices, Character Tables, Diatomic Molecular Orbitals, NH3 Molecular Orbitals, Td Molecular Orbitals, D4h Molecular Orbitals, Pi Donor and Acceptor Ligands, Normal Modes of Vibration, Selection Rules for IR and Raman Spectroscopy, Stretching Frequencies and Structure.   The structure of the ammonia—boryl radical (BH 2 NH 3), an inorganic analogue of the ethyl radical, has been studied at the UHF-SCF level employing the G* basis te geometry optimization has been performed on various possible conformations and the results suggest that the distortion of the BH 2 group is higher than the corresponding distortion of the CH 2 group in the. Stability of inorganic radicals. The inorganic compound nitric oxide (NO) is a stable radical. Fremy's salt (Potassium nitrosodisulfonate, (KSO 3) 2 NO) is a related example. There are also hundreds of examples of thiazyl radicals, despite limited extent of π resonance stabilization.. Radicals form by breaking of covalent bonds by homolytic bond dissociation energies, usually.

  About this book. Over the past few years, radical chemistry has witnessed a rapid development, with the result, for example, that new methods for producing radicals now allow the targeted use of these reactive intermediate stages in organic synthesis. This two-volume work is an account of the progress being made. After reviewing the nature of organic ion-radicals and their ground-state electronic structure, the book discusses their formation, the relationship between electronic structure and reactivity, mechanism and regulation of reactions, stereochemical aspects, synthetic opportunities, and practical applications. The Rules of Inorganic Nomenclature (the 'Red Book'), first published in by the International Union of Pure and Applied Chemistry (IUPAC), was most recently updated as Nomenclature of Inorganic Chemistry This new edition of the Red Book clarifies and updates recommendations concerning the names and formulae of inorganic compounds and reflects major recent developments in inorganic.   Book: Structure & Reactivity in Organic, Biological and Inorganic Chemistry (Schaller) V: Reactivity in Organic, Biological and Inorganic Chemistry 3 The formation of radicals may be driven by the weakness of a particular bond. In terms of radical formation via bond homolysis, the reaction is more product-favored if the bond being broken is.